Careful with shallow and deep metals, I ended up getting zinc, galena, and to rub salt in the wounds, native silver everywhere.
You can use the zinc and lead to power level your blacksmiths / metalcrafters, and silver to make warhammers until you can get better materials off of caravans or dead gobbos.
You are implying that there is a better weapon than a silver warhammer? Naturally the gold and platinum varieties... but talking artifacts is cheating! You'd be best just making everyone a silver hammerer and channeling any other metals into armor. Silver hammers are more or less on par with addy edged weapons from the item testing arena.
To the OP, this is a quote straight form the wiki: "Sedimentary layers are, on average, the most economically valuable of the four stone layers." Not only do they contain -all- iron ores, but they also have two different flux stones as possible layers (dolomite, limestone, and chalk). Aaaaaaaaand it is the only layer that contains coal and lignite. To sweeten the deal, it also contians Kaolinite (porcelain!). As has already been said, outside of igneous extrusive (volcanoes and vents) with its hematite, no other layer type has iron. Considering that sedimentary layers are also the only source of tin... this layer is your make or break for military production... Granted, you have to be near a volcano to lack a sedimentary level, but you could look for "shallow metals" and "flux stone" as your highest priorities when finding a site. Flux stone is notorious for giving false positivies, but if you want iron/steel (or at least bronze) production, you want your richest diversity of metals to be on the surface.